Anodic Cross-Coupling of Biomass Platform Chemicals to Sustainable Biojet Fuel Precursors

Abstract

Electrocatalytic conversion of biomass platform chemicals to jet fuel precursors is a promising approach to alleviate the energy crisis caused by the excessive exploitation and consumption of non-renewable fossil fuels. However, an aqueous electrolyte has been rarely studied. In this study, we demonstrate an anodic electrocatalysis route for producing jet fuel precursors from biomass platform chemicals on Ni-based electrocatalysts in an aqueous electrolyte at room temperature and atmosphere pressure. The desired product exhibited high selectivity for the jet fuel precursor (95.4%) and an excellent coulombic efficiency of 210%. A series of in situ characterizations demonstrated that Ni2+ species were the active sites for the coupling process. In addition, the coupling reaction could be achieved by generating radical cations and inhibiting the side reaction. First, the electrochemical process could activate the furfural (FF) molecule and generate radical cations, resulting in an average of 2.0 times chain propagation. The levulinic acid (LA) molecules played a vital role in the coupling reaction. The adsorption strength of LA on Ni3N was higher than that of FF, which could inhibit the side reaction (the oxidation of FF) and achieve high selectivity. Meanwhile, the LA molecules were adsorbed on the Ni3N surface and then disrupted the formation of Ni3+ species, thus favoring the coupling reaction. This work demonstrates an efficient route to produce jet fuel precursors directly from biomass platform chemicals and provides a comprehensive understanding of the anodic coupling process.

Efficient electrochemical upgradation strategies for the biomass derivative furfural

“…5c. 116 The FF molecule was electrochemically activated to produce free radical cations, and interact with the adsorbed LA to form FDLA on Ni 3 N with a selectivity of 95.4%.…”

“…(c) FF oxidative coupling with LA to FDLA on Ni 3 N, which could further convert into a jet fuel. Adapted with permission 116. Copyright 2022 American Chemical Society.…”

Recent progress of Cu-based electrocatalysts for upgrading biomass-derived furanic compounds

“…17,18 Moreover, they involve a series of radical processes that spawn electro-reductive/oxidative coupling for extending carbon chains. 12,19 The reaction pathways can be modulated towards selective hydrogenation/oxidation by tuning the electrocatalyst surface and working conditions (e.g., potentials, currents, and pH level). Inspired by the catalystdesign principles well documented in conventional thermocatalysis, noble metals (such as Pt, Ag, and Pd) have been applied to the electrochemical refinery of furans.…”

“…17,18 Moreover, they involve a series of radical processes that spawn electro-reductive/oxidative coupling for extending carbon chains. 12,19 The reaction pathways can be modulated towards selective hydrogenation/oxidation by tuning the electrocatalyst surface and working conditions ( e.g. , potentials, currents, and pH level).…”

Mn-doped Ni2P: nanocrystal-decorated amorphous nanosheets for efficient electrooxidation of 5-hydroxymethylfurfural

“…Recently, researchers have paid more and more attention to transition metal catalysts such as transition metal phosphides, sulfides, oxides, hydroxides, and nitrides. [6][7][8][9][10] Among others, nickel phosphide has attracted increasing attention due to its unique electrochemical properties. 11 Unfortunately, the inherent electrocatalytic performance of nickel phosphide in converting HMF to FDCA remains unsatisfactory.…”