Anodic WO<sub>3</sub> Mesosponge @ Carbon: A Novel Binder-less Electrode for Advanced Energy Storage Devices

Pervez, Syed Atif; Kim, Doohun; Doh, Chil‐Hoon; Farooq, Umer; Choi, Hae-Young; Choi, Jeong‐Hee

doi:10.1021/acsami.5b00341

Cited by 78 publications

(38 citation statements)

References 39 publications

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“…Pervez et al. designed a WO 3 mesosponge/carbon composite for LIBs through single‐step electrochemical anodization, followed by annealing in an acetylene and argon atmosphere . The composite material formed a 3D interconnected arrangement of WO 3 mesosponge layers covered with a 5 nm deep layer of carbon on the surface of the tungsten metal.…”

Section: Current Advances In Wo3‐based Batteriessupporting

confidence: 93%

“…[165] The prepared electrode exhibited an excellent Li storage capability,w ith ar eversible capacity of 883.9 mAh g À1 and steady capacity of 351 mAh g À1 after 500 cycles at 1000 mA g À1 .P ervez et al designed aW O 3 mesosponge/carbon composite for LIBs through single-step electrochemical anodization,f ollowed by annealing in an acetylene anda rgon atmosphere. [166] The composite ma-terial formed a3 Di nterconnected arrangement of WO 3 mesosponge layers coveredw ith a5nm deep layer of carbon on the surfaceo ft he tungsten metal. The composite electrode had an excellent electrochemical performance, with ac apacity retention of 87 %o ver 100 cycles.L ie tal.…”

Section: Current Advances In Wo 3 -Based Batteriesmentioning

confidence: 99%

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Review on Recent Progress in the Development of Tungsten Oxide Based Electrodes for Electrochemical Energy Storage

Shinde

2019

ChemSusChem

167

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Current progress in the advancement of energy‐storage devices is the most important factor that will allow the scientific community to develop resources to meet the global energy demands of the 21st century. Nanostructured materials can be used as effective electrodes for energy‐storage devices because they offer various promising features, including high surface‐to‐volume ratios, exceptional charge‐transport features, and good physicochemical properties. Until now, the successful research frontrunners have focused on the preparation of positive electrode materials for energy‐storage applications; nevertheless, the electrochemical performance of negative electrodes is less frequently reported. This review mainly focuses on the current progress in the development of tungsten oxide‐based electrodes for energy‐storage applications, primarily supercapacitors (SCs) and batteries. Tungsten is found in various stoichiometric and nonstoichiometric oxides. Among the different tungsten oxide materials, tungsten trioxide (WO3) has been intensively investigated as an electrode material for different applications because of its excellent charge‐transport features, unique physicochemical properties, and good resistance to corrosion. Various WO3 composites, such as WO3/carbon, WO3/polymers, WO3/metal oxides, and tungsten‐based binary metal oxides, have been used for application in SCs and batteries. However, pristine WO3 suffers from a relatively low specific surface area and low energy density. Therefore, it is crucial to thoroughly summarize recent progress in utilizing WO3‐based materials from various perspectives to enhance their performance. Herein, the potential‐ and pH‐dependent behavior of tungsten in aqueous media is discussed. Recent progress in the advancement of nanostructured WO3 and tungsten oxide‐based composites, along with related charge‐storage mechanisms and their electrochemical performances in SCs and batteries, is systematically summarized. Finally, remarks are made on future research challenges and the prospect of using tungsten oxide‐based materials to further upgrade energy‐storage devices.

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Section: Current Advances In Wo3‐based Batteriessupporting

confidence: 93%

Section: Current Advances In Wo 3 -Based Batteriesmentioning

confidence: 99%

Review on Recent Progress in the Development of Tungsten Oxide Based Electrodes for Electrochemical Energy Storage

Shinde

2019

ChemSusChem

167

View full text Add to dashboard Cite

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“…Carbon materials are commonly used as conductive materials owing to their excellent electronic conductivities and good chemical stabilities. Hence, the construction of nanocomposite of WO 3 with highly conductive carbon materials is widely investigated to enhance the cyclic stability and electrical conductivity of LIBs …”

Section: Tungsten‐based Materials For Libsmentioning

confidence: 99%

Tungsten‐Based Materials for Lithium‐Ion Batteries

Zheng

Tang

et al. 2018

Adv Funct Materials

136

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Lithium-ion batteries are widely used as reliable electrochemical energy storage devices due to their high energy density and excellent cycling performance. The search for anode materials with excellent electrochemical performances remains critical to the further development of lithium-ion batteries. Tungsten-based materials are receiving considerable attention as promising anode materials for lithium-ion batteries owing to their high intrinsic density and rich framework diversity. This review describes the advances of exploratory research on tungsten-based materials (tungsten oxide, tungsten sulfide, tungsten diselenide, and their composites) in lithium-ion batteries, including synthesis methods, microstructures, and electrochemical performance. Some personal prospects for the further development of this field are also proposed.

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“…With a huge potential for alternative electricity generation from intermittent renewable sources such as solar and wind, the need for efficient energy storage system through Li‐ion batteries (LIBs) is getting unprecedented attention . Current LIBs provide the highest gravimetric and volumetric energy densities among other known batteries making them highly suitable for application in portable electronics and electric vehicles . The energy density of LIBs can be increased further by using Li metal as anode material as it offers several times higher specific capacity (≈3.8 Ah g −1 ) and the lowest electrochemical potential (−3.04 V vs SHE).…”

Section: Introductionmentioning

confidence: 99%

Fabrication of a Dendrite‐Free all Solid‐State Li Metal Battery via Polymer Composite/Garnet/Polymer Composite Layered Electrolyte

Pervez

Ganjeh‐Anzabi

Farooq

et al. 2019

Adv Materials Inter

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densities among other known batteries making them highly suitable for application in portable electronics and electric vehicles. [3][4][5][6] The energy density of LIBs can be increased further by using Li metal as anode material as it offers several times higher specific capacity (≈3.8 Ah g −1 ) and the lowest electrochemical potential (−3.04 V vs SHE). However, practical use of Li metal is limited in conventional batteries due to its thermodynamic instability with organic liquid electrolytes, forming dendrites during Li cycling which pose threats of short circuits. Volatility, flammability, and leakage of the liquid electrolytes are additional issues demanding strict attention. [7] Further, the solid electrolyte interphase (SEI) layer formed at the interface cannot withstand mechanical deformation and continuously undergoes formation and dissolution resulting in low Coulombic efficiency (80%-90% for carbonate solvents and 90%-95% for ether solvents) and low cycle life. [8] Most of these issues can be addressed by replacing liquid electrolytes with solid-state electrolytes (SSEs) including organic polymer, or inorganic sulfide or oxide-type. [9][10][11] Among them, oxide SSEs in particular have shown improved electrochemical stability with Li metals. [12] Since the first discovery by Thangadurai et al., [11] garnet-type oxide SSEs (Li 5 La 3 M 2 O 12 (M = Nb, Ta)) have attracted considerable attention due to their highest stability with Li, [12] high Li + transference number (t Li+ ≈ 1), high room temperature ionic conductivities (10 −4 −10 −3 S cm −1 ), and thermal stability at higher temperatures. [12,13] However, with garnet SSEs major challenge lies in realizing intimate Li-SSE contact due to their brittle nature. A poor Li-SSE contact results in high charge-transfer resistance at the interface, which contributes towards high voltage polarizations in the cell. To tackle the issue, various approaches have been adopted such as pressing Li against SSEs at high pressures, [14][15][16] electrolyte surface modifications, [17][18][19] and tuning chemical composition of the SSEs. [20,21] Beside the high interfacial resistance, Li dendrite growth in garnet SSEs is also a cause of concern. In principle garnet SSEs should mechanically block Li dendrites due to their high shear While all-solid-state Li metal batteries based on ceramic solid-electrolytes offer higher energy density and better safety features over their liquid counterparts, critical challenges in their design such as high electrodeelectrolyte interface resistance and formation of Li-dendrites still remain unsolved. To address the issues, an intimate contact between Li and the solid-state electrolyte is necessary. Herein, a flexible and mechanically robust polymer membrane comprising of poly(ethylene oxide), lithium perchlorate, and garnet particles is used as an interlayer between Li metal and garnet ceramic electrolyte. The Li salt enhances the ionic conductivity of the membranes and ensures their flexible nature while garnet particles enhance their mech...

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Anodic WO₃ Mesosponge @ Carbon: A Novel Binder-less Electrode for Advanced Energy Storage Devices

Cited by 78 publications

References 39 publications

Review on Recent Progress in the Development of Tungsten Oxide Based Electrodes for Electrochemical Energy Storage

Review on Recent Progress in the Development of Tungsten Oxide Based Electrodes for Electrochemical Energy Storage

Tungsten‐Based Materials for Lithium‐Ion Batteries

Fabrication of a Dendrite‐Free all Solid‐State Li Metal Battery via Polymer Composite/Garnet/Polymer Composite Layered Electrolyte

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Anodic WO3 Mesosponge @ Carbon: A Novel Binder-less Electrode for Advanced Energy Storage Devices

Cited by 78 publications

References 39 publications

Review on Recent Progress in the Development of Tungsten Oxide Based Electrodes for Electrochemical Energy Storage

Review on Recent Progress in the Development of Tungsten Oxide Based Electrodes for Electrochemical Energy Storage

Tungsten‐Based Materials for Lithium‐Ion Batteries

Fabrication of a Dendrite‐Free all Solid‐State Li Metal Battery via Polymer Composite/Garnet/Polymer Composite Layered Electrolyte

Contact Info

Product

Resources

About

Anodic WO₃ Mesosponge @ Carbon: A Novel Binder-less Electrode for Advanced Energy Storage Devices