Anodically fabricated TiO2 nanopores for electrocatalytic reduction of aldehydes

Babu, K. Firoz; Marxe, K.; Kulandainathan, M. Anbu

doi:10.1016/j.jelechem.2011.09.022

Cited by 7 publications

(3 citation statements)

References 34 publications

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“…Kulandainathan and co-workers prepared nanoporous TiO 2 on Ti foil (TiO 2 /Ti) with increased specific surface area using the electrochemical anodizing method with glycol and NH 4 Cl additives. 65 As shown in Figure 10j−m, the smooth Ti was armed with a rich pore structure after electrochemical anodizing. In addition, electrochemical impedance spectroscopy showed the reduced resistance of Ti/TiO 2 , which facilitated electron transport and mass exchange, thus enhancing the performance of Ti/TiO 2 .…”

Section: Modified Electrodesmentioning

confidence: 99%

Section: Electrocatalytic Reduction Of Furfuralmentioning

confidence: 99%

“…Besides electrodeposition, the sol–gel method can also increase the specific surface areas of electrodes. Kulandainathan and co-workers prepared nanoporous TiO 2 on Ti foil (TiO 2 /Ti) with increased specific surface area using the electrochemical anodizing method with glycol and NH 4 Cl additives . As shown in Figure j–m, the smooth Ti was armed with a rich pore structure after electrochemical anodizing.…”

Section: Electrocatalytic Reduction Of Furfuralmentioning

confidence: 99%

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Recent Advances in Furfural Reduction via Electro- And Photocatalysis: From Mechanism to Catalyst Design

Wen,

Zhang,

Fan

et al. 2023

ACS Catal.

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Furfural has been considered as one of the most attractive biomass platform compounds, which can be valorized into high-value-added chemicals (e.g., hydrofurorin, 2methyl furan, tetrahydrofurorin, furfuryl alcohol, tetrahydrofurfuryl alcohol, and 2methyltetrahydrofuran) and upgraded to functional materials (e.g., synthetic resins, electrical insulation materials, nylon, coatings, and pharmaceuticals). Although the traditional thermocatalytic transformation of furfural is effective, it always requires harsh conditions, especially high temperature and pressure. Accordingly, the reduction of furfural via electro-and photocatalytic approaches has gradually attracted tremendous attention and achieved remarkable progress. Herein, this Review systematically emphasizes the recent advancements in catalysts for valorizing furfural into high-value-added chemicals, biofuels, and additives through electro-and photocatalysis. Moreover, the design strategies of different reactors (i.e., H-cells and flow cells) are clarified. In addition, the application of advanced operando/in situ characterizations and theoretical calculations are highlighted to gain insights into the reaction pathways and catalytic mechanism of the electro-and photocatalytic reduction of furfural. Finally, the current challenges and perspectives are outlined in the field of electro-and photocatalytic furfural conversion.

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Section: Modified Electrodesmentioning

confidence: 99%

Section: Electrocatalytic Reduction Of Furfuralmentioning

confidence: 99%

Section: Electrocatalytic Reduction Of Furfuralmentioning

confidence: 99%

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Recent Advances in Furfural Reduction via Electro- And Photocatalysis: From Mechanism to Catalyst Design

Wen,

Zhang,

Fan

et al. 2023

ACS Catal.

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Recent Advances in Selective Chemical Etching of Nanomaterials for High‐Performance Electrodes in Electrocatalysis and Energy Storage

Campbell,

Brown,

Nguyen

et al. 2024

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To move beyond an energy economy dominated by fossil fuel utilization, high‐performance electrochemical cells must be designed for energy storage and conversion. Selective etching is a promising, cost‐effective solution‐processing method for the large‐scale top‐down production of nanomaterials for high‐performance electrodes. This review outlines general methodologies and mechanisms by which selective etching can be applied to create nanomaterials, including various template‐assisted, facet‐selective, and electrochemical methods, as well as in‐depth case studies of state‐of‐the‐art research involving selectively etched nanomaterials for electrocatalytic and energy storage applications. In addition, the standard design strategies by which the electrochemical performance of selectively etched nanomaterials is enhanced, including increased surface area, morphology, diffusion channels, heterojunction interfaces, and facet reactivity, are discussed. This review provides a foundation of knowledge for researchers seeking the rational design of nanomaterials for electrode application through selective etching.

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Electrochemical oxidation of 4-chlorophenol for wastewater treatment using highly active UV treated TiO2 nanotubes

et al. 2018

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Anodically fabricated TiO2 nanopores for electrocatalytic reduction of aldehydes

Cited by 7 publications

References 34 publications

Recent Advances in Furfural Reduction via Electro- And Photocatalysis: From Mechanism to Catalyst Design

Recent Advances in Furfural Reduction via Electro- And Photocatalysis: From Mechanism to Catalyst Design

Recent Advances in Selective Chemical Etching of Nanomaterials for High‐Performance Electrodes in Electrocatalysis and Energy Storage

Electrochemical oxidation of 4-chlorophenol for wastewater treatment using highly active UV treated TiO2 nanotubes

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