Anomalous Anisotropic Dopant Distribution in Hexagonal Yttrium Sublattice

Abstract

Trivalent lanthanides are commonly incorporated into sodium yttrium fluoride nanocrystals to enhance their optical properties. Lanthanides are expected to randomly replace trivalent yttrium cations due to their isovalent nature, and the dopant−dopant distance decreases with increasing dopant concentration. Combining spectroscopy with quantum mechanical calculations, we find that large lanthanides exhibit an anisotropic distribution in the hexagonal yttrium sublattice at low dopant concentrations. This counterintuitive substitution suggests the formation of one-dimensional dimers or chains with short dopant−dopant distances. Our study of the distance-sensitive cross-relaxation between Nd 3+ dopants in β-NaYF 4 nanocrystals confirms that the concentration quenching threshold is lower than that of their cubic counterparts, consistent with the proposed chain-like model. Moreover, we demonstrate modulation of the anisotropic distribution by microstrain management via alkali metal codoping. Research into dopant distribution in inorganic crystals may enable the development of new materials and properties for future challenges.

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