“…In PNAS, Urban et al (1) have carefully observed precisely this process in a sample space partially filled with liquid helium initially in near equilibrium with its saturated vapor; specifically, a complex heat flow within the system results from the application of a high heat flux to the bottom plate of the sample space and, a short time later, is accompanied by an inversion of temperature, such that heat is seen to flow from a colder body-the bottom heated plate-to a now hotter one-the cooled upper plate. That the second law of thermodynamics remains unchallenged by these observations is attributable mainly to the fact that the dominant heat-transport mechanisms in the transient process involve changes of phase, specifically boiling and condensation, in a system that is closed, although not isolated from the external environment, and is maintained far from equilibrium.…”