The positive ion mobility in superfluid 3 He has been measured under high magnetic fields up to 14.6 T over the wide pressure region. It increases rapidly below the transition temperatures in both superfluid A 1 and A 2 phases. The magnetic field dependence exhibits an anomalous behavior which is sensitive to the liquid pressure, especially above 20 bar. The behavior is similar to that observed recently in the normal phase at 3.2 mK. This fact indicates that the exchange spin scattering between the positive ion and the 3 He quasiparticles does exist both in the normal and superfluid 3 He phase.