In the process of talent selection and evaluation, it is important to know the personality traits, ability, knowledge level, and development potential of the candidates. However, the above evaluation indicators are difficult to describe with precise values, and personnel evaluation often needs to be done through group decision making (GDM). In this paper, we establish a GDM method under the interval‐valued intuitionistic fuzzy (IVIF) environment based on Dombi aggregation operations, which are the extension of existing operations. First, IVIF operations are introduced. Second, a series of IVIF Dombi aggregation operators are proposed, such as IVIF Dombi weighted averaging operator, IVIF Dombi‐ordered weighted averaging (IIFDOWA) operator, IVIF Dombi geometric weighted geometric (IIFDWG) operator, and IVIF Dombi‐ordered weighted geometric (IIFDOWG). The desirable properties of these proposed aggregation operators are well studied. Finally, the GDM method based on these Dombi aggregation operators under the IVIF environment is presented; the case study about personnel evaluation based on the proposed method is presented to show its validity and rationality. The comparison with other methods is presented to show the difference and advantage of the GDM method proposed in this paper.