The contentious issue in ArF lithography is to reduce cost with multi-patterning process. To achieve low defectivity is required at high speed scanner for increasing throughput. Especially, demand of applying topcoat (TC) less process is being increasing recent year at using high speed scanner. The hydrophobic film surface is preferred because less immersion defect is caused without remaining water droplet in exposure. For positive-tone development (PTD) by using alkaline developer, the polarity-change property function of film surface from hydrophobic to hydrophilic after alkaline development process is key to reduce defectivity. High alkaline-responsive materials which were not only polymer additives but also copolymers as main component of resist have good potential to defectivity reducing. Additionally, to suppress swelling is one of very impotent factor to improve bridge type defect mode.