Anti-corrosion performance of a new silane coating for corrosion protection of AZ31 magnesium alloy in Hank's solution

Zomorodian, Amir; Brusciotti, Fabiola; Fernandes, Anabela C.; Carmezim, M.J.; Silva, Teresa M.; Fernandes, João; Montemor, M.F.

doi:10.1016/j.surfcoat.2012.04.061

Cited by 113 publications

(75 citation statements)

References 32 publications

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“…In many instances, a dry gel needs further thermal treatment to be densified [20]. The sol-gel process versatility allows incorporation of additional components that introduce material's complementary functionalities, such as UV protection [21,22], anti-fouling [23,24], anti-reflection [25][26][27][28][29], moisture resistance [29][30][31][32][33], corrosion and adhesion protection [34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50][51][52][53], along with the enhancement of mechanical, thermal, and optical properties, opening a wide range of application in several fields of science. Furthermore, this method allows the control of several experimental conditions leading to a simple sequence that may be tuned to the nature, final shape, and desired function.…”

Section: General Background Of Sol-gel Coatings For Corrosion Mitigationmentioning

confidence: 99%

Hybrid Sol-Gel Coatings: Smart and Green Materials for Corrosion Mitigation

et al. 2016

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Corrosion degradation of materials and metallic structures is one of the major issues that give rise to depreciation of assets, causing great financial outlays in their recovery and or prevention. Therefore, the development of active corrosion protection systems for metallic substrates is an issue of prime importance. The promising properties and wide application range of hybrid sol-gel-derived polymers have attracted significant attention over recent decades. The combination of organic polymers and inorganic materials in a single phase provides exceptional possibilities to tailor electrical, optical, anticorrosive, and mechanical properties for diverse applications. This unlimited design concept has led to the development of hybrid coatings for several applications, such as transparent plastics, glasses, and metals to prevent these substrates from permeation, mechanical abrasion, and corrosion, or even for decorative functions. Nevertheless, the development of new hybrid products requires a basic understanding of the fundamental chemistry, as well as of the parameters that influence the processing techniques, which will briefly be discussed. Additionally, this review will also summarize and discuss the most promising sol-gel coatings for corrosion protection of steel, aluminium, and their alloys conducted at an academic level.

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Section: General Background Of Sol-gel Coatings For Corrosion Mitigationmentioning

confidence: 99%

Hybrid Sol-Gel Coatings: Smart and Green Materials for Corrosion Mitigation

et al. 2016

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“…The silanol groups undergo a self-crosslinking process through siloxane bonds (Si-O-Si). As a result, the organic coating layer is chemically bonded to the metal substrate 7 . In regards to the corrosion science, a lot of effort has been made to apply these materials as adhesion promoters between metallic substrates and organic coatings used for protection against the corrosion phenomena 8,9 .…”

Section: Introductionmentioning

confidence: 99%

Effect of Tetraethoxy-silane (TEOS) Amounts on the Corrosion Prevention Properties of Siloxane-PMMA Hybrid Coatings on Galvanized Steel Substrates

et al. 2015

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Siloxane-poly(methyl methacrylate) (PMMA) organic-inorganic hybrid coatings were deposited on galvanized steel by the dip-coating sol-gel technique. Anticorrosion properties, as well as the morphological, surface and structural features were studied. Hybrid coatings were synthesized from tetraethoxy-silane (TEOS) and methyl methacrylate (MMA) as inorganic and organic phases, respectively, linked by 3-metacriloxypropyl-trimethoxysilane (TMSM) as a coupling agent. The MMA/TMSM ratio was kept constant, whereas the four TEOS/TMSM ratios were varied. The characterization of coatings was assessed using several techniques such as Scanning Electronic Microscopy (SEM), Contact Angle, Fourier Transform Infrared (FT-IR), Open Circuit Polarization (OCP), Atomic Force Microscopy (AFM) and Electrochemical Impedance Spectroscopy measurements (EIS). The EIS results, which were obtained for the hybrid coatings, were discussed based on an electrical equivalent circuit used to adjust the experimental data. The results showed that the increasing the TEOS content caused increase in coating thickness, increased in the surface roughness and increased in the surface hydrophobicity. The film with the highest TEOS content presented the best electrochemical performance, more effective in protecting against corrosion.

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“…Aiming for biomedical applications, many kinds of surface modification techniques are applied to Mg alloys, such as various Ca-P coatings [11][12][13][14], micro-oxidation coatings [15], fluoride coatings [16], biodegradable polymer coatings [17,18], silanization [19] or a combination of anodization and silanization [20]; their main purpose is to improve corrosion resistance of Mg alloys.…”

Section: Introductionmentioning

confidence: 99%

Surface characterization and cytocompatibility evaluation of silanized magnesium alloy AZ91 for biomedical applications

Witecka

Yamamoto

Dybiec

et al. 2012

Science and Technology of Advanced Materials

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Mg alloys with high Al contents have superior corrosion resistance in aqueous environments, but poor cytocompatibility compared to that of pure Mg. We have silanized the cast AZ91 alloy to improve its cytocompatibility using five different silanes: ethyltriethoxysilane (S1), 3-aminopropyltriethoxysilane (S2), 3-isocyanatopyltriethoxysilane (S3), phenyltriethoxysilane (S4) and octadecyltriethoxysilane (S5). The surface hydrophilicity/hydrophobicity was evaluated by water contact angle measurements. X-ray photoelectron analysis was performed to investigate the changes in surface states and chemical composition. All silane reagents increased adsorption of the albumin to the modified surface. In vitro cytocompatibility evaluation revealed that silanization improved cell growth on AZ91 modified by silane S1. Measurement of the concentration of Mg 2+ ions released during the cell culture indicated that silanization does not affect substrate degradation.

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Anti-corrosion performance of a new silane coating for corrosion protection of AZ31 magnesium alloy in Hank's solution

Cited by 113 publications

References 32 publications

Hybrid Sol-Gel Coatings: Smart and Green Materials for Corrosion Mitigation

Hybrid Sol-Gel Coatings: Smart and Green Materials for Corrosion Mitigation

Effect of Tetraethoxy-silane (TEOS) Amounts on the Corrosion Prevention Properties of Siloxane-PMMA Hybrid Coatings on Galvanized Steel Substrates

Surface characterization and cytocompatibility evaluation of silanized magnesium alloy AZ91 for biomedical applications

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