We present the weak-lensing and optical analysis of the SL2S-ARCS (SARCS) sample of strong-lensing candidates. The sample is based on the Strong Lensing Legacy Survey (SL2S), a systematic search of strong-lensing systems in the photometric CanadaFrance-Hawaii Telescope Legacy Survey (CFHTLS). The SARCS sample focusses on arc-like features and is designed to contain mostly galaxy groups. We briefly present the weak-lensing methodology that we used to estimate the mass of the SARCS objects. Among 126 candidates, we obtained a weak-lensing detection (at the 1σ level) for 89 objects with velocity dispersions of the singular isothermal sphere mass model (SIS) ranging from σ SIS ∼ 350 km s −1 to ∼1000 km s −1 with an average value of σ SIS ∼ 600 km s −1 , corresponding to a rich galaxy group (or poor cluster). From the galaxies belonging to the bright end of the group's red sequence (M i < −21), we derived the optical properties of the SARCS candidates. We obtained typical richnesses of N ∼ 5−15 galaxies and optical luminosities of L ∼ 0.5−1.5 × 10 12 L (within a radius of 0.5 Mpc). We used these galaxies to compute luminosity density maps, from which a morphological classification reveals that a large fraction of the sample (∼45%) are groups with a complex light distribution, either elliptical or multi-modal, suggesting that these objects are dynamically young structures. We finally combined the lensing and optical analyses to define a sample of the 80 most secure group candidates, i.e. weak-lensing detection and over-density at the lens position in the luminosity map, to remove false detections and galaxy-scale systems from the initial sample. We use this reduced sample to probe the optical scaling relations in combination with a sample of massive galaxy clusters. We detect the expected correlations over the probed range in mass with a typical scatter of ∼25% in σ SIS at a given richness or luminosity, making these scaling laws interesting mass proxies.