Anticorrosion effect of a green sustainable inhibitor on mild steel in hydrochloric acid

Vicia faba peel extracts bearing fatty acids moieties as a cost-effective and green corrosion inhibitor for mild steel in marine water: computational and electrochemical studies

“…To create a chemisorbed layer, the neutral molecules that are present in the primary elements of each extract must first displace the molecules of water that are adsorbed to the surface of the metal. Inhibition of corrosion of mild steel by either extract in a solution containing 3.5% www.nature.com/scientificreports/ sodium chloride may be rationalized based on molecular adsorption [93][94][95] . These chemicals prevent corrosion by regulating the processes that occur during both the anodic and cathodic phases.…”

Synergetic Anticorrosion Mechanism of Main Constituents in Chinese Yam Peel for Copper in Artificial Seawater

“…Particularly, the constant phase angle elements ( Q f and Q dl for the electrolyte/barrier layer and the barrier layer/copper interfaces, respectively) were used, rather than pure capacity, to compensate the dispersion effect caused by interfacial heterogeneity, whose impedance ( Z Q ) could be expressed as where Y 0 is the proportional coefficient; j is the imaginary root; ω is the angular frequency, rad/s; and n denotes an exponent that measures the interfacial deviation from the perfect capacitance . Considering the noteworthy capacitive characteristic illustrated in the Bode modulus (Figure b), interfacial capacitances, namely, the film capacitance ( C f ) and the double layer capacitance ( C dl ), were calculated as per the following equations where f max is the frequency at which the imaginary impedance reaches a maximum, Hz. Based on the impedance traits, the spectra for copper without and with 100, 300, and 500 mg/L CYPE in ASW were fitted by the circuit in Figure a, while the other circuit in Figure b is suitable for the remaining spectra.…”

“…Conforming with the sustainable awareness, commendable biomass-derived products as corrosion inhibitors possess salient advantages including biocompatibility, nontoxicity, and availability, to name just a few . Since the utilization of the Chelidonium majus extract as a corrosion inhibitor in 1930, naturally occurring extracts have become a quickly growing family as an important green strategy for retarding the unexpected metal dissolution in various corrosive environments. Typically, Ahmed and Zhang utilized the Atriplex leucoclada extract to inhibit copper corrosion in 1 M HCl solution, which behaved as a mixed-type inhibitor and adsorbed onto the substrate via monolayer assembly.…”

Effective corrosion inhibition of mild steel in hydrochloric acid by newly synthesized Schiff base nano Co(ii) and Cr(iii) complexes: spectral, thermal, electrochemical and DFT (FMO, NBO) studies

“…50 The inhomogeneity of the examined steel surface during the EIS experiments is frequently linked to the depressed semi-circle shape of the Nyquist plots. 51 The presence of Co(II)-L or Cr(III)-L molecules haven't impacted the semi-circle shapes, however the width of the semicircles was enlarged as the complexes concentration increased, implying that the corrosion reaction mechanism wasn't modied and therefore, the adsorption of the complex molecules must be occurred on the steel surface and evidently the adsorbed lm thickness was gradually increased by increasing of the complexes concentration. The EIS results were tted with a suitable equivalent circuit utilizing Echem Analyst soware to determine the most suitable circuit elements that aligns the experimental EIS results.…”