Antimony-Coated Carbon Nanocomposites as High-Performance Anode Materials for High-Temperature Sodium–Metal Batteries

Abstract

Metallic sodium (Na) possesses several advantageous characteristics, including a high theoretical specific capacity, low electrode potential, and availability in abundance, making it an ideal anode material for sodium−metal batteries (SMBs). However, the practical use of Na metal anodes is severely impeded due to the uncontrolled formation of dendrites due to the slow electrochemical kinetics and chemical instability of the formed solid-electrolyte interphase (SEI) layer. This situation can worsen considerably under high-temperature (HT) conditions (>55 °C).To overcome this issue, we have fabricated a thermally stable antimony (Sb)-coated carbon (Sb@C) nanocomposite as a sodium host material, where Sb nanoparticles are encapsulated within the carbon layers. This unique nanostructure controls vaporization during the plating-stripping process and dendrite formation and provides acceptor sites for Na + ions. The Sb@C electrode exhibits an extended life span of symmetrical cycles (2400 h at 1 mA cm −2 ) due to the abundant nucleation sites. It maintains a low nucleation overpotential (∼15 mV), enhancing its performance and long cycle stability. Moreover, the in situ formed Na−Sb synergistically offers durable ionic/electronic diffusion paths and chemically interacts with Na, forming abundant Na nucleation sites. Therefore, in this study, we emphasize the importance of the rational design of highly stable alloys and present an effective strategy for achieving high-performance sodium−metal anodes.

Review of Nanoarrays in Lithium Metal Anodes

“…The inherent lithiophobic nature of 2D copper foils and the high current density affect the Li + flux in the LMA, allowing lithium dendrites and “dead Li” to form rapidly . According to the Space Charge Model, the uncontrolled growth of lithium dendrites is attributed to uneven ion flux and local current density. , According to Sand’s time theory, dissipating local current density to suppress dendrite growth can be achieved through a three-dimensional framework with high specific surface area. − Therefore, to adapt to the “host-less” characteristics, it is essential to build a good framework of ion channels and Li hosts to achieve long-term stable operation of the battery. − Therefore, 3D current collectors with large specific surface areas, multiple active sites, and the ability to adjust electric field gradients to better control local current density are being widely studied. 3D current collectors, which have been widely reported recently, can solve these problems.…”