2021
DOI: 10.1002/adma.202102958
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Antiperovskite Gd3SnC: Unusual Coexistence of Ferromagnetism and Heavy Fermions in Gd Lattice

Abstract: Inverted structures of common crystal lattices, referred to as antistructures, are rare in nature due to their thermodynamic constraints imposed by the switched cation and anion positions in reference to the original structure. However, a stable antistructure formed with mixed bonding characters of constituent elements in unusual valence states can provide unexpected material properties. Here, a heavy‐fermion behavior of ferromagnetic gadolinium lattice in Gd3SnC antiperovskite is reported, contradicting the c… Show more

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