In this paper, g-C3N4-based hydrogel
with
a 3D network structure was synthesized via a simple and cheap reaction,
using hydroxyethyl cellulose (HEC) and graphitic carbon nitride (g-C3N4) as the main materials. Electron microscope
images revealed that the microstructure of g-C3N4-HEC hydrogel was rough and porous. The luxuriant scaly textures
of this hydrogel were due to the uniform distribution of g-C3N4 nanoparticles. It was found that this hydrogel showed
great removal ability of bisphenol A (BPA) through a synergistic effect
of adsorption and photodegradation. The adsorption capacity and degradation
efficiency of g-C3N4-HEC hydrogel (3%) for BPA
were 8.66 mg/g and 78% under the conditions of C
0 = 9.94 mg/L and pH = 7.0, which were much higher than those
for the original g-C3N4 and HEC hydrogel. In
addition, g-C3N4-HEC hydrogel (3%) exhibited
excellent removal efficiency (98%) of BPA (C
0 = 9.94 mg/L) in a dynamic adsorption and photodegradation
system. Meanwhile, the mechanism of removal was investigated in depth.
The superior batch and continuous removal capability of this g-C3N4-based hydrogel make it promising for environmental
applications.