Sulfur transformations in sewer networks are predominantly of importance because of the formation and occurrence of hydrogen sulfide. Hydrogen sulfide related to wastewater in sewers is a worldwide problem as it leads to concrete and metal corrosion, odor nuisance and human health impacts. The solution to these problems has its starting point in an understanding of the sewer network as a reactor for physical, chemical and biological sulfur processes that govern the formation of hydrogen sulfide and its control. In this respect, it becomes important to predict the interacting sulfur processes in terms of both simple empirical equations and more advanced models that are based on a conceptual understanding of the sulfur processes, the latter is of particular importance when applied to the complex constructed and functioning sewers of today. Problems related to sewer gases have been known for centuries. However, no more than about 100 years ago, based on sound scientific and technical knowledge, it was recognized that corrosion and odor problems in wastewater collection systems are closely related to anaerobic conditions and a corresponding formation of hydrogen sulfide. In brief, sulfide formation takes place by the activity of anaerobic sulfate-reducing bacteria that are mainly found in sewer biofilms from where sulfide penetrates the wastewater phase (see also Chapter 5). It is the subsequent emission of hydrogen sulfide into the sewer atmosphere that