Apparent molar volumes (V Φ ) of hexane-1,2,3,4,5,6-hexol in aqueous solutions of 1-and 2-propanols were obtained from densities of ternary solutions, accurately measured with a quartz vibrating-tube densimeter at several temperatures in the range from (293.15 to 313.15) K. Refractive indexes (n D ) measurements were also made for hexane-1,2,3,4,5,6-hexol + propanol + water at T ) 298.15 K. The data of V Φ have been used to deduce the limiting partial molar volumes of hexane-1,2,3,4,5,6-hexol (V 0 Φ ) and limiting partial molar volumes of transfer (∆ trs V 0 Φ ) from water to different alcohol solutions at different concentrations. From the values of n D , molar refractive indexes (R D ) were calculated. Then the changes of these parameters were discussed in the light of interaction between solute and solvent and the different locations of the hydroxyl group in propanol isomers.