This work investigates the performance of isooctyl glucoside
(APG08)
as an emulsifier for the preparation of a Karamay heavy crude oil-in-water
emulsion to facilitate its pipeline transportation. First, various
factors affecting the rheology and stability of prepared emulsions
were studied. The results revealed that the viscosity and stability
of emulsions increased with increasing oil content, surfactant concentration,
mixing speed, mixing time, and pH of the aqueous phase. Emulsion viscosity
was initially unchanged with the increase in homogenization temperature
and then increased while emulsion stability decreased. Meanwhile,
the optimal values of key parameters were 75 wt % oil content, 0.5
wt % surfactant concentration, temperature of 30 °C, mixing speed
of 750 rpm, mixing time of 10 min, and aqueous phase pH of 11.14,
resulting in a viscosity reduction of 88.82% and emulsion stability
up to 48 h at 96.27%. In addition, a qualitative relationship between
the stability and rheology of emulsions was elaborated by analyzing
the experimental results. The findings showed that an increase in
emulsion stability was accompanied by an increase in emulsion viscosity.
Therefore, emulsion viscosity cannot become very high while improving
emulsion stability to ensure proper transportation.