“…Laser‐induced breakdown spectroscopy (LIBS) and Raman spectroscopy are two famous spectral techniques because of their advantages in rapid, online, and in‐site detection. [ 1,2 ] As a new elemental detection method, LIBS has been used in identification of many kinds of substance with chemometrics, for instance, biomedical samples, [ 3–5 ] forensic evidences, [ 6–9 ] explosives, [ 10 ] plants, [ 11 ] alloy, [ 12 ] ore, [ 13 ] nutrient food, [ 14–16 ] and pathogenic microorganisms. [ 17 ] However, for substances with the same elemental composition, the feature line wavelengths are always similar.…”