Low-voltage pulsed electric fields, corresponding to field strengths
of 2–16 V/cm, were utilized for mass transfer intensification
of drops in a liquid–liquid extraction process. The chemical
system of kerosene–acetic acid–water was used in which
mass transfer resistance lies mainly in the kerosene phase. The applied
frequencies were within 100–1000 Hz. In a hydrodynamic study,
the circulating state of drops was confirmed based on different criteria
and their terminal velocity precisely followed the Grace model. A
mass transfer study of drops, on the other hand, revealed the strong
impact of a pulsed electric field with the average and maximum enhancements
of 30.3 and 70.5%. This can be attributed to the interfacial instability
due to switching poles in the pulsed electric field. An optimum frequency
of about 300 Hz corresponded to the applied voltages. Applying a direct
electric field also had desired effects but in a lower extent. The
provided mass transfer coefficient data were reproduced based on the
Kumar and Hartland correlation together with a developed correlation
of the enhancement factor in terms of dimensionless field strength,
frequency, and the drops’ Reynolds number. The maximum deviation
between experimental and predicted Sherwood numbers was ±5%.