Application of electron-transfer chain catalysis: preparation of bridged 〚{(η5-C5H5)Fe(CO)2}2(μ-diphosphine)2+〛 complexes without chelated 〚(η5-C5H5)Fe(CO)(η2-diphosphine)+〛 byproducts

Peng, James; Liu, Ling‐Kang

doi:10.1016/s1631-0748(02)01384-x

Search citation statements

Order By: Relevance

Paper Sections

Select...

Synthesis and Spectroscopical Characterization1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2007

2012

Publication Types

Select...

Article4

Relationship

Self Cite0

Independent4

Authors

Journals

Cited by 4 publications

(1 citation statement)

References 30 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A special feature of our ligand 3 that could be responsible for the fact that 3 does not readily adopt a chelating coordination mode, is its reducing power [3]. [28]. Electron-transfer chain processes thus appear to suppress the formation of the chelate complex [CpFe(CO)-g 2 -dppe]I, and a similar effect may be operative also in our case.…”

Section: Synthesis and Spectroscopical Characterizationmentioning

confidence: 71%

The first bidentate phosphanylborohydride: Synthesis, structure, and reactivity towards [CpFe(CO)2I]

Dornhaus

Bolte

Lerner

2007

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Section: Synthesis and Spectroscopical Characterizationmentioning

confidence: 71%

The first bidentate phosphanylborohydride: Synthesis, structure, and reactivity towards [CpFe(CO)2I]

Dornhaus

Bolte

Lerner

2007

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Synthesis and characterization of amine complexes of the cyclopentadienyliron dicarbonyl complex cation, [Cp(CO)2Fe]+

M’thiruaine

Friedrich

Changamu

et al. 2011

Inorganica Chimica Acta

View full text Add to dashboard Cite

[{CpFe(CO) 2 } 2 l-(NH 2 (CH 2 ) n NH 2 )](BF 4 ) 2 (n = 2-4) (3), respectively. These complexes have been fully characterized and the mass spectral patterns of complexes 2 are reported. The structures of compounds 2a (n = 2) and 2b (n = 3) have been confirmed by single crystal X-ray crystallography. The single crystal X-ray diffraction data show that complex 2a, [CpFe(CO) 2 NH 2 (CH 2 ) 2 CH 3 ]BF 4 , crystallizes in a triclinic P 1 space group while 2b, [CpFe(CO) 2 NH 2 (CH 2 ) 3 CH 3 ]BF 4 , crystallizes in an orthorhombic Pca2 1 space group with two crystallographically independent molecular cations in the asymmetric unit. Furthermore, the reaction of 1 with 1-alkenes gives the g 2 -alkene complexes in high yield.

show abstract

1,1′-Bis(diphenylphosphino)ferrocene bridging two mono(cyclopentadienyl) cobalt moieties: Synthesis, structure, electrochemistry and DFT studies

Rosa

Realista

Mourato

et al. 2012

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Application of electron-transfer chain catalysis: preparation of bridged 〚{(η5-C5H5)Fe(CO)2}2(μ-diphosphine)2+〛 complexes without chelated 〚(η5-C5H5)Fe(CO)(η2-diphosphine)+〛 byproducts

Cited by 4 publications

References 30 publications

The first bidentate phosphanylborohydride: Synthesis, structure, and reactivity towards [CpFe(CO)2I]

The first bidentate phosphanylborohydride: Synthesis, structure, and reactivity towards [CpFe(CO)2I]

Synthesis and characterization of amine complexes of the cyclopentadienyliron dicarbonyl complex cation, [Cp(CO)2Fe]+

1,1′-Bis(diphenylphosphino)ferrocene bridging two mono(cyclopentadienyl) cobalt moieties: Synthesis, structure, electrochemistry and DFT studies

Contact Info

Product

Resources

About