Application of Energy-Saturated Complex Perchlorates

Ilyushin, M. A.

doi:10.1063/1.2337203

Cited by 2 publications

(1 citation statement)

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“…Prominent examples of heterocycles applied as ligands are found in Grubbs I and Grubbs II catalysts as well as in B vitamins, with their most prominent representative being vitamin B 12 . A recently emerged, closely related field of research is that of energetic coordination compounds (ECCs) used in pyrotechnic mixtures, burn rate modifiers, and primary explosives . Here, energetic and nitrogen-rich heterocycles are combined with transition-metal salts of oxidizing ( e.g.…”

Section: Introductionmentioning

confidence: 99%

1-(Nitratomethyl)-5H-tetrazole: A Highly Sensitive Ligand with Improved Oxygen Balance for Laser-Ignitable Coordination Compounds

et al. 2022

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For the first time, the highly sensitive 1-(nitratomethyl)-5H-tetrazole (1-NAMT) was synthesized, representing the shortest possible 1-(nitratoalkyl)-5H-tetrazole with a combined nitrogen and oxygen content of 81.4%. Compared to its related ethyl derivative, 1-(nitratoethyl)-5H-tetrazole, it exhibits improved oxygen balance, resulting in higher detonation parameters. 1-NAMT was thoroughly analyzed by single-crystal diffraction experiments accompanied by elemental analysis, IR spectroscopy, and multinuclear (1H, 13C, and 14N) NMR measurements. The thermal behavior of 1-NAMT was analyzed by differential thermal analysis supported by thermogravimetric analysis. Furthermore, energetic coordination compounds (ECCs) of Cu with different inorganic (e.g., nitrate, chlorate, and perchlorate) and nitroaromatic anions (e.g., picrate and styphnate) were synthesized and thoroughly analyzed. It is shown that the formation of ECCs with nitroaromatic anions (T dec ∼ 180 °C) is a suitable strategy to improve the rather low thermal stability of 1-NAMT (125 °C).

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Section: Introductionmentioning

confidence: 99%