“…It is on this part of the trajectory, where the kinetic energy and the density of the flow are both high enough to excite the nitrogen dissociation at reaction rates which lead to dissociation lengths in the order of magnitude of the characteristic geometrical length and the chemical composition of the gas is in a nonequilibrium state. After this regime of a high deceleration, which can be simulated with respect to the duplication of characteristic chemical relaxation and flow lengths in a free piston driven shock tunnel, the kinetic energy of the flow is too low to excite the dissociation of molecules, especially nitrogen, and the chemical composition of the flow remains frozen, f2 -Even if there exists no vehicle flying with very high velocities at low altitudes, where the combination of a high kinetic energy and a high density would justify the assumption that the chemical composition of the flow is in chemical equilibrium, this assumption has been applied to the nonequilibrium flow regime to assess high temperature real gas effects on the shock/shock interaction phenomena (see for example Stewart et al (1988)). …”