Comprehensive studies of the phase composition of refractory concrete compositions heat-treated in different temperature intervals, including the operating range of glassmaking equipment, have been performed. The characteristic changes of the phase composition of unsintered concretes during the transformative heat-treatment have been established; a new phase appears after sintering at 1000°C -calcium aluminosilicate 2CaO × Al 2 O 3 × SiO 2 , which attests to the interaction in the sample of calcium aluminates with free silicamicrosilica or aluminosilicates.