2012
DOI: 10.1002/jms.3110
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Application of LC‐MS and LC‐MS‐MS to the analysis of photo‐decomposed crystal violet in the investigation of cultural heritage materials aging

Abstract: In this work, the accurate liquid chromatography-ultraviolet-visible (LC-UV-Vis), LC-mass spectrometry (MS) and LC-MS-MS analysis of the photo-degradation products of crystal violet (CV) is reported. CV is a light fugitive early synthetic dye which had a widespread diffusion into the market starting from the end of the XIX century and was used among others by V. Van Gogh and P. Gauguin in their writings, drawings or paintings. On-line photodiode array detector enabled simultaneous UV-Vis spectra acquisition. M… Show more

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Cited by 43 publications
(39 citation statements)
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“…In addition, it saw a widespread diffusion as an artist material starting from the end of the 19th century and was used among the others by Vincent Van Gogh and Paul Gauguin in their writings, drawings, and paintings. [5,6] Tryarylmethane dyes were probably introduced in Asia soon after their invention, as suggested by their ubiquitous use in the woodblock prints of the Meiji periods shown in this article.…”
Section: Introductionmentioning
confidence: 96%
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“…In addition, it saw a widespread diffusion as an artist material starting from the end of the 19th century and was used among the others by Vincent Van Gogh and Paul Gauguin in their writings, drawings, and paintings. [5,6] Tryarylmethane dyes were probably introduced in Asia soon after their invention, as suggested by their ubiquitous use in the woodblock prints of the Meiji periods shown in this article.…”
Section: Introductionmentioning
confidence: 96%
“…Despite their wide range of applications, triarylmethane dyes are extremely sensitive to light exposure. A series of studies have dealt with the identification of the photo‐degradation processes and the chemical modifications caused by light exposure, under different conditions . It has been noticed that the degradation of CV and MV strongly depends on light fluence …”
Section: Introductionmentioning
confidence: 99%
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