Application of magnetic resonance spectroscopies to the characterisation of elastomer/filler systems

Legrand, A.P.

doi:10.1002/masy.19961080108

Cited by 6 publications

(4 citation statements)

References 21 publications

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“…Figure 2 shows schematically the various possibilities of polymer chain attachments to the filler particles. 4 Chain segments E, F, and D are not affected directly by the macroscopic deformation.…”

Section: Introductionmentioning

confidence: 99%

“…As well as the susceptibility of the carbon black filler, we also consider that the applied macroscopic deformation does not affect the chains closely attached to filler particles to the same degree as it does the remaining chains. Figure shows schematically the various possibilities of polymer chain attachments to the filler particles . Chain segments E, F, and D are not affected directly by the macroscopic deformation.…”

Section: Introductionmentioning

confidence: 99%

“…

1 (a) NMR spectrum from a carbon black filled deformed poly(butadiene) network (λ = 1.80) showing the asymmetry in the peak heights. (b) NMR spectrum from an unfilled deformed network (λ = 1.83) showing the symmetry in the peak heights.

2 Model of the filler−elastomer interactions: cb, carbon black; A, physical attachment; B, chemical attachments; C, cross-linked rubber chain; D, loose fold; E, tight fold; F, multiple adsorptive attachments; G, interparticle tie chain; H, cilium; I, entanglements (from ref ).

3 Schematic diagram showing how the resultant asymmetric NMR spectrum is formed from two symmetric signals. (a) NMR spectrum from segments not in the vicinity of the carbon black particles.…”

Section: Introductionmentioning

confidence: 99%

“…Model of the filler−elastomer interactions: cb, carbon black; A, physical attachment; B, chemical attachments; C, cross-linked rubber chain; D, loose fold; E, tight fold; F, multiple adsorptive attachments; G, interparticle tie chain; H, cilium; I, entanglements (from ref ).…”

Section: Introductionmentioning

confidence: 99%

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Susceptibility Effect of Carbon Black Filler on the Deuterium NMR Line Shape from Poly(butadiene) Networks

Ekanayake¹,

Menge²,

Schneider³

et al. 2000

Macromolecules

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Deuterium NMR line shapes of carbon black (N220) filled cis-1,4-poly(butadiene) networks have been examined. The effect of the susceptibility of the filler on the NMR line shape has been considered. The theory proposed by Brereton and Ries for deuterium NMR line splitting in spectra of polymer networks was used to fit the experimental data. It was found that the polymer segments near the surface of a filler particle experience a different local magnetic field from the remaining segments, due to the susceptibility of the carbon black. This effect gives rise to an asymmetry in the NMR spectrum, which until now has not been explained. Additionally, this analysis determines the fraction of polymer units affected by the local field of the filler particles and provides information about the effect of the macroscopic deformation on these attached chains.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

“…

3 Schematic diagram showing how the resultant asymmetric NMR spectrum is formed from two symmetric signals. (a) NMR spectrum from segments not in the vicinity of the carbon black particles.…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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