Application of metal complexes as biomimetic catalysts on glycerol oxidation

Parodi, Adrián R.; Merlo, Carolina; Córdoba, Agostina; Palopoli, Claudia; Ferreyra, Joaquín; Signorella, Sandra; Ferreira, Marı́a Luján; Magario, Ivana

doi:10.1016/j.mcat.2018.11.007

Cited by 2 publications

(1 citation statement)

References 72 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The alternative of employing iron-based catalysts and hydrogen peroxide as oxidant is gaining importance for the liquid phase oxidation of glycerol under mild conditions (base-free, ambient temperature, and atmospheric pressure). , Crotti and Farnetti performed the glycerol oxidation in an acetonitrile/water mixture using homogeneous iron complexes associated to the tridentate ligand bis(2-pyridinylmethyl)amine (BPA) as catalyst. They reported that high selectivity toward DHA or formic acid could be achieved by tuning operating conditions.…”

Section: Clean Catalytic Oxidation Of Alcoholsmentioning

confidence: 99%

Clean Catalytic Oxidation for Derivatization of Key Biobased Platform Chemicals: Ethanol, Glycerol, and Hydroxymethyl Furfural

Ayude

Doumic

Cassanello

et al. 2019

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

There has been a growing interest in the last decades in technologies that transform biomass-derived feedstock into renewable chemicals. A group of target molecules derived from biomass as key intermediates between raw materials and final products have been designed as "platform chemicals". Sustainable processes involve the use of renewable feedstock, but also pursue low energy consumption, the use of less hazardous materials, and diminished generation of waste. This review aims to present recent advances on environmentally friendly catalytic oxidation routes for transforming three platform chemicals, ethanol, glycerol, and 5-hydroxymethylfurfural, to value added intermediates and final products using air or oxygen as oxidants and water without additives (base-free) as solvent, and preferably under moderate operating conditions. Works carried out under continuous flow have been particularly reviewed.

show abstract

Section: Clean Catalytic Oxidation Of Alcoholsmentioning

confidence: 99%