Application of Metal–Organic Frameworks in Fine Chemical Synthesis

Canivet, J.; Farrusseng, David

doi:10.1002/9783527658985.ch10

Cited by 3 publications

(1 citation statement)

References 155 publications

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“…The hybrid organic–inorganic materials known as metal–organic frameworks (MOFs), above all their porous subset, are continuously gaining ground in scientific research, especially due to their interesting and promising functionalities, e.g., magnetic, optical, electrical, redox, and luminescence properties, as well as, when permanent porosity is present, gas adsorption or separation, catalytic activity, and drug delivery . In the realm of porous MOFs, ultrahigh porosity, provided by architectures with exceptionally large pores and apertures, smart catalysis within the pores, gas adsorption for alternative fuels, gas separation for clean air, and proton conductivity for fuel cell applications constitute some of the current hot topics, which renders it obvious the huge importance that MOFs potentially possess in numerous industrial applications.…”

Section: Introductionmentioning

confidence: 99%

Bis(pyrazolato)-Based Metal–Organic Frameworks Fabricated with 4,4′-Bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)biphenyl and Late Transition Metals

Tăbăcaru

Pettinari

Marchetti

et al. 2014

Crystal Growth & Design

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The reaction between the flexible, bis-(pyrazolato)-based ligand 4,4′-bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)biphenyl (H 2 DMPMB) and late transition metal ions allowed the isolation of the two series of thermally stable metal−organic frameworks [M(DMPMB)] (M = Co, Zn, Cd) and [M 2 (DMPMB)] (M = Cu, Ag). X-ray powder diffraction (XRPD) structure determinations demonstrated that the anti conformation adopted by the ligand, juxtaposed to its exotetradentate coordination mode, induces the formation of a 3-D architecture with nonpervious 1-D channels in the three isomorphous species [M(DMPMB)] and of corrugated 2-D layers in [Cu 2 (DMPMB)]. Coupling thermogravimetric analyses and variable temperature XRPD highlighted that the five materials are thermally stable at least up to 300 °C, both under nitrogen and in air, the Cd(II) derivative decomposing only at the remarkably high temperature of 500 °C. No thermal event could be detected; all the materials preserve their structural motifs up to decomposition. The adsorption properties of the five compounds were assayed toward N 2 at 77 K: while no adsorption was observed for [Cd(DMPMB)], the other species possess estimated BET and Langmuir specific surface areas in the ranges 64(1)−526(3) m 2 /g and 142(4)−713(27) m 2 /g, respectively, thus being an example of the interesting phenomenon known as "porosity without pores". Finally, the luminescence properties of the Zn(II), Cd(II), and Cu(I) derivatives were investigated.

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Section: Introductionmentioning

confidence: 99%

Bis(pyrazolato)-Based Metal–Organic Frameworks Fabricated with 4,4′-Bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)biphenyl and Late Transition Metals

Tăbăcaru

Pettinari

Marchetti

et al. 2014

Crystal Growth & Design

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Framework‐Copper‐Catalyzed C−N Cross‐Coupling of Arylboronic Acids with Imidazole: Convenient and Ligand‐Free Synthesis of N‐Arylimidazoles

Devarajan

Suresh

2016

ChemCatChem

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A convenient and environmentally benign synthesis of N‐arylimidazoles has been demonstrated by a straightforward reaction catalyzed by the unsaturated coordination sites of Cu in the copper terephthalate metal–organic framework (Cu(tpa)‐MOF). A series of N‐arylimidazoles has been synthesized in excellent yields by the C−N cross‐coupling reaction of arylboronic acids and imidazoles catalyzed by the Cu(tpa)‐MOF using ethanol as a benign solvent. The present ligand‐free catalytic system proceeds smoothly under mild conditions, avoids stoichiometric Cu reagents, tolerates many functional groups, has a wide substrate scope, and is feasible with other nitrogen heterocycles. The stability and heterogeneity of the catalyst is evidenced by the results of a heterogeneity test, and the catalyst can be reused several times without a loss of activity. The easy preparation of the catalyst, its stability, recovery by simple filtration, and reusability reveal Cu(tpa) MOF as a versatile catalyst for academic and industrial applications.

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Recent reports on vanadium based coordination polymers and MOFs

Gupta¹

2022

Reviews in Inorganic Chemistry

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Coordination polymers (CP) and metal-organic frameworks (MOF) have become a topic of immense interest in this century primarily because of the structural diversity that they offer. This structural diversity results in their multifaceted utility in various fields of science and technology such as catalysis, medicine, gas storage or separation, conductivity and magnetism. Their utility inspires a large variety of scientists to engage with them in their scientific pursuit thus creating a buzz around them in the scientific community. Metals capable of forming CPs and MOFs are primarily transition metals. Among them vanadium-based CPs and MOFs demand detailed discussion because of the unique nature of vanadium which makes it stable in many oxidation states and coordination number. Vanadium’s versatility imparts additional structural marvel and usefulness to these CPs and MOFs.

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Application of Metal–Organic Frameworks in Fine Chemical Synthesis

Cited by 3 publications

References 155 publications

Bis(pyrazolato)-Based Metal–Organic Frameworks Fabricated with 4,4′-Bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)biphenyl and Late Transition Metals

Bis(pyrazolato)-Based Metal–Organic Frameworks Fabricated with 4,4′-Bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)biphenyl and Late Transition Metals

Framework‐Copper‐Catalyzed C−N Cross‐Coupling of Arylboronic Acids with Imidazole: Convenient and Ligand‐Free Synthesis of N‐Arylimidazoles

Recent reports on vanadium based coordination polymers and MOFs

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