Application of microwave dielectric loss heating effects for the rapid and convenient synthesis of organometallic compounds

Direct in situ synthesis of cationic N-heterocyclic carbene iridium and rhodium complexes from neat ionic liquid: Application in catalytic dehydrogenation of cyclooctadiene

“…di-l-chloro-bis(g 4 -1,5-cyclooctadiene)-dirhodium(I), di-l-chloro-bis(g 4 -1,5-cyclooctadiene)diiridium(I); di-l-acetato-bis(g 4 -1,5-cyclooctadiene)dirhodium(I); di-l-acetato-bis(g 4 -1,5-cyclooctadiene)-diiridium(I); g 4 -1,5-cyclooctadiene-l-2,4-pentanedionato-rhodium(I): l-2,4-pentanedionato-g 4 -1,5-cyclooctadiene-iridium(I); bis(g 4 -1,5-cyclooctadiene)di-lethanoatodirhodium(I); bis(g 4 -1,5-cyclooctadiene)di-l-ethanoatodiiridium(I); chloro -g 4 -1,5-cyclooctadienetriphenylphosphinerhodium(I) were carried out as described in the literature [30][31][32]38].…”

Applications of microwave dielectric heating in environment-related heterogeneous gas-phase catalytic systems

“…The research has been focused on the application of microwave dielectric heating in a range of chemical processes including the synthesis of superconducting ceramics [31] and other inorganic materials [33][34][35][36][37][38][39][40][41], the synthesis of organometallic compounds [42,43], solid-state reactions involving metal powders [44][45][46][47][48], and more recently heterogeneous catalytic reactions [49][50][51][52][53][54][55]. Advances have also been made in understanding dielectric heating behaviour [24,29,50,52,56].…”

Complexes of Ruthenium and Osmium Containing η2–η6 Hydrocarbon Ligands: (iii) Complexes Containing Six-, Seven- and Eight-membered Rings

“…The formation of the benzene and p-cymene complexes from ethanolic RUC1 3 JCH 2 O and cyclohexadiene and ct-phellandrene, respectively, is markedly accelerated by microwave heating. 45 ' 46 …”