The
hydration and swelling of shale caused by water in water-based
drilling fluids is one of the most important problems that causes
wellbore instability. The development of high-performance shale inhibitors
is an important prerequisite for ensuring the drilling of shale formations.
In this study, four deep eutectic solvents (DESs) based on choline
chloride (urea-DES, Gly-DES, Oxa-DES, and Cit-DES) were synthesized
and introduced as promising shale inhibitors. Fourier transform infrared
spectroscopy (FT-IR) and hydrogen nuclear magnetic resonance spectroscopy
(1H NMR) were used to characterize the structural information
on DESs. The inhibition ability of DESs was evaluated by a bentonite
inhibition test, a linear swelling test, and a settlement test. Compared
with the traditional inhibitors, such as potassium chloride (KCl)
and polyether amine, the four DESs can effectively inhibit the hydration
and swelling of shale. Five wt % DESs can maintain low rheological
parameters when the content of sodium bentonite (Na-bent) was as high
as 40 wt %. Among them, Gly-DES not only exhibited the most efficient
inhibition capability but also had the advantage of not affecting
the basic performance of the drilling fluid. Inhibitory mechanism
analysis showed that the electrostatic interaction and hydrogen bonding
between DESs and sodium bentonite (Na-bent) are the most important
factors to inhibit clay hydration. Besides, the reduction of the surface
tension of the liquid by DESs effectively weakened the driving force
for water to penetrate the Na-bent layer. Finally, it is important
to note that, although DESs exhibited strong inhibitory capabilities,
some DESs, such as Oxa-DES and Cit-DES, are prone to adversely affect
the basic performance of drilling fluids. Therefore, a careful selection
is required.