Application of the Cathode-Ray Oscilloscope to Polarographic Phenomena. III. Potentials of Adsorption–Desorption Capacity Peaks and Surface Charge Density Relationships Exhibited by Alcohols at Aqueous Saline Solution–Mercury Interfaces

Lovel, J. West; Elving, Philip J.

doi:10.1021/j150500a002

J. Phys. Chem.

1952

DOI: 10.1021/j150500a002

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Application of the Cathode-Ray Oscilloscope to Polarographic Phenomena. III. Potentials of Adsorption–Desorption Capacity Peaks and Surface Charge Density Relationships Exhibited by Alcohols at Aqueous Saline Solution–Mercury Interfaces

J. West Lovel¹,

Philip J. Elving²

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1962

1976

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Cited by 21 publications

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The properties of the electrical double layer at a dropping mercury electrode in n‐potassium chloride containing n‐alkyltrimethylammonium ions

Meakins

1967

J. Appl. Chem.

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In further experiments on the adsorption of n‐alkyltrimethylammonium corrosion inhibitors at a dropping mercury electrode in N‐potassium chloride solution, the potential applied to the dropping mercury electrode was taken as far as ‐1.9 volts S.C.E. The electrocapillary and differential capacitance curves for n‐dodecyl‐and n‐hexadecyltrimethylammonium bromides in N‐potassium chloride were generally similar to those in N‐sulphuric acid, and the calculated surface concentrations of the adsorbed quaternary ammonium ions were almost the same. The wider range of potential in the present experiments enabled the desorption peaks in the differential capacitance curves for the more dilute solutions to be demonstrated. The stronger solutions gave subsidiary peaks, or steps, which may be associated with the formation of double or multiple layers. The results of these and previous experiments are explained on the basis that the adsorbed layer of n‐alkyltrimethylammonium ions does not completely exclude solvated ions, but hinders their approach to the metal surface.

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The properties of the electrical double layer at a dropping mercury electrode in n‐potassium chloride containing n‐alkyltrimethylammonium ions

Meakins

1967

J. Appl. Chem.

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Tensammetric studies of alcohols with reference to their structural influence on surface activity

Gupta

Sharma

1963

Kolloid-Z.u.Z.Polymere

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Die Bedeutung der kritischen Micellkonzentration bei der Elektrosorptionsanalyse von Aniontensiden mit der Wechselstrompolarographie

Vollbardt¹

1976

Colloid Polymer Sci

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Application of the Cathode-Ray Oscilloscope to Polarographic Phenomena. III. Potentials of Adsorption–Desorption Capacity Peaks and Surface Charge Density Relationships Exhibited by Alcohols at Aqueous Saline Solution–Mercury Interfaces

Cited by 21 publications

References 0 publications

The properties of the electrical double layer at a dropping mercury electrode in n‐potassium chloride containing n‐alkyltrimethylammonium ions

The properties of the electrical double layer at a dropping mercury electrode in n‐potassium chloride containing n‐alkyltrimethylammonium ions

Tensammetric studies of alcohols with reference to their structural influence on surface activity

Die Bedeutung der kritischen Micellkonzentration bei der Elektrosorptionsanalyse von Aniontensiden mit der Wechselstrompolarographie

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