When used in combination with source management strategies, monitored natural attenuation (MNA) is likely to be a technically feasible remediation option if the contaminant persistence time along the flow path is less than (a) the transport time to the compliance point and (b) the time available for groundwater remediation objectives to be achieved. Biodegradation is often the most significant natural attenuation process for benzene, toluene, ethylbenzene, and xylenes (BTEX) in groundwater. While BTEX transport rates increase with groundwater velocity, examination of data obtained from the published literature for seven sites undergoing MNA revealed significant positive correlations between groundwater velocity and first-order biodegradation rates for toluene (r ϭ 0.83, P Ͻ 0.05), ethylbenzene (r ϭ 0.93, P Ͻ 0.01), m-and p-xylene (r ϭ 0.96, P Ͻ 0.01), and o-xylene (r ϭ 0.78, P Ͻ 0.05). This is attributed to increased dispersion at higher velocities leading to more mixing of electron acceptors with the contaminant plume. There was no positive correlation between groundwater velocity and first-order biodegradation rates for benzene due to noise in the relationship caused by variations in (a) the concentrations of electron acceptors in the uncontaminated groundwater and (b) the proportions of benzene in the total BTEX concentration in the source area.A regression model of the relationship between groundwater velocity and the first-order biodegradation rate can be used to delineate operating windows for groundwater velocity within which the contaminant persistence time is less than the transport and remediation times for a given source concentration, target concentration, distance to compliance point, retardation factor, and remediation time. The operating windows can provide decision makers with a rapid indication of whether MNA is likely to be a technically feasible remediation option at a given site. © 2005 Wiley Periodicals, Inc.
INTRODUCTIONThe Environment Agency (EA) for England and Wales has published technical guidance on the assessment and monitoring of natural attenuation of contaminants in groundwater (R&D Publication 95;Carey et al., 2000). However, demonstrating that monitored natural attenuation (MNA) is likely to be a technically feasible remediation option during the "screening" stage of R&D Publication 95 can be difficult if there is insufficient information available at this stage of the remediation project.Therefore, the application of MNA may be overlooked at sites where it could be effective.A solution to this problem is the delineation of operating windows for MNA (Scott & Nathanail, 2004 (i.e., technically feasible). It is envisaged that operating windows could be delineated from MNA case study data, such as that available in the published literature, and used by decision makers to provide an indication of the technical feasibility of MNA at a given site based on site characterization data obtained early in the risk assessment process.This article demonstrates a methodology for the delineation...