Application of the tetraphenylphosphonium tetraphenylborate (TPTB) assumption to the thermodynamic properties of solvated ions in dimethylsulfoxide

Warmińska, Dorota; Stangret, Janusz

doi:10.1039/c2cp23051h

Cited by 5 publications

(1 citation statement)

References 31 publications

(46 reference statements)

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“…Extra thermodynamic models must be used for the determination of single ion thermodynamic quantities [2,3].…”

Section: Introductionmentioning

confidence: 99%

Gibbs Free Energies, Enthalpies and Entropies of Transfer for Reference Ions Ph4 As+ and Ph4 B- in Mixed DMFA-H2O Solvents at Different Temperatures

Gomaa¹

2012

AJEE

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The thermodynamic data ( ∆ G t , ∆ H t and T ∆ S t ) of transfer for tetraphenylarsonium-tetraphenylborate (Ph 4 AsBPh 4 ) from water to mixed dimethylformamide (DMFA)-H 2 O solvents were estimated from the experimental solubility and calorimeter measurements. The experiments were done at three different temperatures 288.15, 298.15 and 308.15 K. Also the thermodynamic parameters were divided into reference anion and cation following the asymmetric deviation and their values, were discussed. Dividing all the thermodynamic functions between the cation and anion by using 1.064 factors we obtain their individual functions. The reference ion values can be easily used for evaluating the different thermodynamic parameters of any ion that contains in its counterion tetraphenyl cation or anion . By using the data given here the thermodynamic parameters for some single ion can be estimated for following their behaviour in environment. The single ion thermodynamics are helpful for predicting, explaining and mechanisms suggesting. Theoretical and engineering chemistry are in need for experimental single ion parameters for the comparison with that calculated by different solvation theories.

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“…Extra thermodynamic models must be used for the determination of single ion thermodynamic quantities [2,3].…”

Section: Introductionmentioning

confidence: 99%

Gibbs Free Energies, Enthalpies and Entropies of Transfer for Reference Ions Ph4 As+ and Ph4 B- in Mixed DMFA-H2O Solvents at Different Temperatures

Gomaa¹

2012

AJEE

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A Computational Study on 3‐Azonia‐, 3‐Phosphonia‐, and 3‐Arsoniaspiro[2.2]pentanes and Related Three‐Membered Heterocycles

et al. 2014

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A theoretical study at the ab initio MP2/6‐311++G(d,p) level of theory is carried out to characterize several heterocyclic spiro[2.2]pentane cations with N, P, and As as spiro atoms. The strain and relative stability of the spiropentanes are obtained through isodesmic reactions. Nucleus‐independent chemical shifts (NICS) and 3D NICS isosurfaces show σ‐aromatic characteristics, similar to those found in cyclopropane. The interaction with the Cl− anion, which results in four different stationary structures, is studied and characterized by means of the atoms in molecules methodology, and Cl⋅⋅⋅pnicogen, Cl⋅⋅⋅H, and Cl⋅⋅⋅C interactions are found. The most stable structure in all cases corresponds to opening of one of the three‐membered rings, due to the attack of the Cl atom, and CCl bond formation. Furthermore, the reaction with the 3‐boranuidaspiro[2.2]pentane anion results in the formation of a new compound through cleavage of one ring of both reactants.

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Solvation Numbers of Divalent Metal Salts and Ions in Some Non-aqueous Solvents

Marcus

2016

J Solution Chem

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Application of the tetraphenylphosphonium tetraphenylborate (TPTB) assumption to the thermodynamic properties of solvated ions in dimethylsulfoxide

Cited by 5 publications

References 31 publications

Gibbs Free Energies, Enthalpies and Entropies of Transfer for Reference Ions Ph<SUB>4</SUB> As<SUP>+</SUP> and Ph<SUB>4</SUB> B<SUP>-</SUP> in Mixed DMFA-H<SUB>2</SUB>O Solvents at Different Temperatures

Gibbs Free Energies, Enthalpies and Entropies of Transfer for Reference Ions Ph<SUB>4</SUB> As<SUP>+</SUP> and Ph<SUB>4</SUB> B<SUP>-</SUP> in Mixed DMFA-H<SUB>2</SUB>O Solvents at Different Temperatures

A Computational Study on 3‐Azonia‐, 3‐Phosphonia‐, and 3‐Arsoniaspiro[2.2]pentanes and Related Three‐Membered Heterocycles

Solvation Numbers of Divalent Metal Salts and Ions in Some Non-aqueous Solvents

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