Application of μRaman Microscopy to the Identification of Individual Airborne Particles: Preliminary Results from Kozani's Area, Northern Greece

Iordanidis, Andreas; García-Guinea, Javier; Garas, Stylianos; Asvesta, Argyro; Triantafyllou, A. G.

doi:10.1080/02726351.2013.878772

Cited by 4 publications

(1 citation statement)

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“…Source apportionment studies focused on the long-distance transport of aerosols have effectively used MRS. A study over Kozani, Northern Greece [85] showed the existence of various mineral phases in the collected aerosols, such as calcite (1084, 710, 274, and 149 cm −1 ), gypsum (1134, 1006, and 413 cm −1 ), titanium oxide (627, 390, and 148 cm −1 ), feldspar (510, 474,285, 265, 150, and 109 cm −1 ), lepidolite (1573, 1347, 728, 382, and 288 cm −1 ), and smectite (1379, 731, 385, 288, and 141 cm −1 ). The presence of lepidolite (mica) and smectite (clay) was associated with the long-distance transport of Saharan dust.…”

Section: Ambient Aerosol Studiesmentioning

confidence: 99%

Single-Particle Analysis of Atmospheric Aerosols: Applications of Raman Spectroscopy

et al. 2022

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Atmospheric aerosols, produced as a consequence of different anthropogenic and natural processes, impart significant control over the global energy budget, climate, and human–environmental health. Their size varies across the nano–micrometer scale. Based on their origin, they may be classified into primary or secondary aerosols. Biomass burning, incomplete combustion of fossil fuels, volcanic eruptions, and traffic-related and wind-driven suspensions contribute to primary aerosol emissions. In contrast, gas-to-particle conversion within the atmosphere leads to secondary particle production. The study of atmospheric aerosols is vital to the field of atmospheric research. The dynamic nature (highly variable concentration composition and size with space and time) of aerosols makes them difficult to investigate. Today, aerosol research involves the application of various spectrometric and spectroscopic techniques. The single-particle analysis of aerosols is yet a challenge. In this review, the merits and demerits of various offline and online techniques used for aerosol research are discussed in a nutshell. Mass spectrometric techniques fail in distinguishing certain species. However, Raman spectroscopy’s emergence for the compositional analysis of aerosols resolves most of the present characterization challenges. This review focuses on Raman spectroscopy applications, the merits of this technique, and its immense scope for the measurement of various types of aerosols and their properties. Surface-enhanced Raman spectroscopy (SERS) has an advantage over conventional micro-Raman spectroscopy (MRS). The review depicts the dominance of SERS, specifically in the context of the measurement of ambient atmospheric aerosols. This review discusses two important components, namely laboratory simulation and ambient aerosol studies.

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Section: Ambient Aerosol Studiesmentioning

confidence: 99%