New subclasses of bi-univalent functions with bounded boundary rotation are presented in this study. We acquired estimates for the initial coefficients a2, a3 and a4. Furthermore, we have verified the specific situations satisfying the famous hypothesis of Brannan and Clunie. Additionally, we have obtained the well-known Fekete–Szegö inequality for the newly identified bi-univalent function subclasses. Our results not only improve, but also extend several existing results as particular cases.