We report on electronic collective excitations in RMn 2 O 5 (R= Pr, Sm, Gd, Tb) showing condensation starting at and below ~T N~TC~4 0-50 K. Its origin is understood as partial delocalized e g electron orbitals in the Jahn-Teller distortion of the pyramids dimmer with strong hybridized Mn 3+ -O bonds. Our local probes, Raman, infrared, and X-ray absorption, back the conclusion by which there is no structural phase transition at T N~TC . Ferroelectricity is magnetically assisted by electron localization triggering lattice polarizability by unscreening.We have also found phonon hardening as the rare earth is sequentially replaced.