Chang 8 section of Yanchang Group in Yuancheng area of Ordos Basin is a typical tight oil reservoir in China, which is characterised by low porosity and low permeability, strong non-homogeneity and high difficulty in evaluating reservoir parameters. In order to clarify the microscopic pore structure characteristics of the Chang 8 section, this study uses cast thin section, scanning electron microscope, combined with the core physical properties test data, to analyse the basic characteristics of the reservoir rock mineralogy, pore permeability and other basic characteristics, and uses the shape of piezo-mercury curves to study the pore structure characteristics of the 17 samples. Based on the fractal dimension of the NMR T2 spectrum, the reservoir is classified into four categories, and a conversion model for the relationship between the NMR T2 spectrum and the capillary pressure curve is established by using the segmented power function method, which is applied to the interpretation of the NMR logging to obtain the continuous pseudo-capillary pressure curve for the whole well section. Three effective parameters reflecting the microscopic pore structure, namely, the expulsion pressure, median pressure, and sorting coefficient of the core samples, were extracted, and the relationship between the reservoir parameters and the reservoir category was established by using the generalised regression neural network. The pseudo-capillary pressure curve reservoir parameters of the whole well section were processed to obtain the classification profile of the reservoir, and the classification results were consistent with the results of the mercury pressure experiment with good results. The study shows that this method can provide an important basis for the study of pore structure of tight oil reservoirs and the evaluation of reservoir classification.