Applications of the crystalline sponge method and developments of alternative crystalline sponges

Habib, Faiza; Tocher, Derek A.; Carmalt, Claire J.

doi:10.1016/j.matpr.2022.01.018

Cited by 8 publications

(4 citation statements)

References 114 publications

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“…59,61 Following the initial publication of the crystalline sponge method, considerable work has been carried out to optimise the preparation of the crystalline sponge crystals. 62,[64][65][66][67][68] Most notably, Clardy and co-workers were able to reduce synthesis time for single crystal crystalline sponges (suitable for guest analysis) from a total of 14 days to 3 days through use of the more volatile solvent chloroform, instead of nitrobenzene, in the crystal growth step. By using chloroform, the crystals formed did not require the solvent exchange step and were instead ready for immediate use in guest soaking.…”

Section: Preparation Of Single Crystal Crystalline Sponges: Synthesis...mentioning

confidence: 99%

Advanced crystallisation methods for small organic molecules

et al. 2023

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Section: Preparation Of Single Crystal Crystalline Sponges: Synthesis...mentioning

confidence: 99%

Advanced crystallisation methods for small organic molecules

et al. 2023

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“…This shows that business applications for MOF are gaining a lot of traction. As seen in A variety of uses for MOF include catalysis [192], gas separation [193], drug delivery systems [194,195], imaging, sensing, molecular conductors [196], gas separation [197], energy storage [198] and structural determination [199,200]. Due to its porous nature, MOF is a very significant class of material with an unequalled degree of tunability.…”

Section: Mof-based Nanomaterials For Supercapacitorsmentioning

confidence: 99%

Metal-organic framework based nanomaterials: An advanced review of their synthesis and energy storage applications

Yatoo

Gupta

Habib

et al. 2023

Preprint

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Metal-organic frameworks (MOFs) have emerged as a versatile class of porous materials with enormous potential for various applications, including energy storage devices. In this review, we present a comprehensive analysis of the recent advancements and applications of MOFs in the field of energy storage. We begin by providing a brief overview of the fundamental aspects of MOFs, including their synthesis, structural diversity, and tuneable properties. We then focus on the utilisation of MOFs in advanced energy storage systems with a particular focus on supercapacitors. MOFs can be employed as electrode materials, separators, and catalysts, offering enhanced electrochemical performance, improved charge/discharge rates, and prolonged cycling stability. The unique tunability of MOFs allows for the rational design of tailored materials with desired properties, such as high specific capacity, excellent conductivity, and superior cycling stability. We will further discuss in detail the recent developments in MOF-based electrochemical capacitors, highlighting the significant progress made in achieving high energy and power densities. The exceptional charge storage capacity of MOFs combined with their facile synthesis and scalability make them promising candidates for next-generation energy storage technologies. The review further sheds light on the challenges and opportunities in the practical implementation of MOFs in energy storage devices with an eye on future research and development in the MOFs for energy applications. The manuscript discusses perspectives and future directions and, we believe, the insights presented are timely and will be of particular help to young and early-stage researchers.

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“…Some of the most notable applications have included the combination of CS with high-performance liquid chromatography for analysis of human metabolites, or the study of natural products that requires only nanograms of sample for molecular structure elucidation (Rosenberger et al, 2020;Inokuma et al, 2013). Two extensive recent reviews further discuss the underlying principles and applications of CS analysis (Zigon et al, 2021;Habib et al, 2022).…”

Section: Introductionmentioning

confidence: 99%

Statistical optimization of guest uptake in crystalline sponges: grading structural outcomes

Carroll,

Coles

2024

IUCrJ

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Investigation of the analyte soaking conditions on the crystalline sponge {[(ZnI2)3(tpt)2·x(solvent)] n } method using a statistical design of experiments model has provided fundamental insights into the influence of experimental variables. This approach focuses on a single analyte tested via 60 experiments (20 unique conditions) to identify the main effects for success and overall guest structure quality. This is employed as a basis for the development of a novel molecular structure grading system that enables the quantification of guest exchange quality.

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Applications of the crystalline sponge method and developments of alternative crystalline sponges

Cited by 8 publications

References 114 publications

Advanced crystallisation methods for small organic molecules

Advanced crystallisation methods for small organic molecules

Metal-organic framework based nanomaterials: An advanced review of their synthesis and energy storage applications

Statistical optimization of guest uptake in crystalline sponges: grading structural outcomes

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