Applications of the Methylene Insertion Reaction to Component Analysis of Hydrocarbons.

Dvoretzky, Isaac; Richardson, D. B.; Durrett, L. R.

doi:10.1021/ac60197a002

Cited by 21 publications

(1 citation statement)

References 17 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The MIR (17)(18)(19) can be applied in all cases where methyl-substituted derivatives of known hydrocarbons are to be made (20). The resulting number of isomeric species and to some extent also their quantitative ratios depend on the number of different types of CH bonds contained in the original hydrocarbon.…”

mentioning

confidence: 99%

Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats Indexes

Schomburg¹,

Dielmann²

1973

Anal. Chem.

View full text Add to dashboard Cite

mentioning

confidence: 99%

Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats Indexes

Schomburg¹,

Dielmann²

1973

Anal. Chem.

View full text Add to dashboard Cite

Cyclooligomerisationen an Übergangsmetall‐Katalysatoren

Heimbach

1973

Angewandte Chemie

View full text Add to dashboard Cite

In diesem Fortschrittsbericht werden auljer neuartigen Ringsynthesen und Darstellungswegen fur Derivate bekannter Ringe auch neuartige Katalysatorsysteme vorgestellt, z. B. auf der Basis von Nickel, Eisen, Molybdiin, Mangan und Palladium. Am Beispiel der Identifizierung mono-und dimethyl-substituierter acht-, zehn-und zwolfgliedriger Ringe laBt sich exemplarisch die breite Verwendbarkeit der Methyleneinschiebungsreaktion zeigen. Ein weiterer Abschnitt befaljt sich mit dem moglichen Reaktionsablauf der C-C-Verknupfungen in Ubergangsmetall-Komplexen. Einige friihere Annahmen wurden aufgrund neuerer Experimente revidiert. Auljerdem werden experimentelle Hinweise auf die unterschiedliche Reaktivitat und Selektivitat der Komplexe aus Nickel-Ligand-Katalysator und Olefiien oder Alkinen je nach Struktur der Liganden diskutiert.

show abstract

Cyclooligomerization with Transition Metal Catalysts

Heimbach

1973

Angew. Chem. Int. Ed. Engl.

View full text Add to dashboard Cite

This report is concerned not only with the syntheses of new ring systems and the preparation of derivatives of known rings but also with new types of catalysts based upon, e.g., nickel, iron, molybdenum, manganese, and palladium. The broad applicability of the methylene insertion reaction as a method for identifying monoand di-methyl-substituted eight-, ten-, and twelve-,membered rings is also demonstrated. A further section is concerned with the possible mechanism of C-C bond formation in transition metal complexes; several earlier suggestions have been revised in the light of new experimental data. In addition, experimental results are discussed which indicate that the reactivity and selectivity of the complexes formed by the nickel-ligand catalyst and olefins or alkynes depend upon the structure of the ligands. A number of interesting syntheses have likewise been carried out starting from cis-1,2-divinyIcyclobutane. A few examples are shown in eq. (62)['641. 0s: 1 + COOR -COOH J COOR ROOC COOR COOR COOR 0 I wish to express tit!' thanks, also on behalf ofmy co-workers, to the Director of the Max-Planck-Institut f iir Kohlenforsckung ProJ Dr. G. Wilke for his support of our work and for many useful suggestions. In particular I gratefully acknowledge continuingfinancial and academic support even after my acceptance of a position at the Gesamtkochsckule Essen. I also wish to acknowledge the friendly assistance

show abstract

Applications of the Methylene Insertion Reaction to Component Analysis of Hydrocarbons.

Cited by 21 publications

References 17 publications

Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats Indexes

Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats Indexes

Cyclooligomerisationen an Übergangsmetall‐Katalysatoren

Cyclooligomerization with Transition Metal Catalysts

Contact Info

Product

Resources

About