A set of orthonormal color matching functions is developed, in which the first is an all-positive achromatic function, the second is red-green, and the third can be loosely described as blue-yellow. The achromatic function, proportional to the familiar y, is a sum of red and green cones. The red-green function uses the same cone sensitivities, but subtracted, with coefficients so that it is orthogonal to the achromatic one. The third function involves all three cones, but is primarily a blue sensitivity. Using this basis to compute the tristimulus vectors of narrow-band lights at unit power gives Jozef Cohen's locus of unit monochromats, (LUM) an invariant shape now graphed in a space where the axes have intuitive meaning. The extreme points of the LUM reveal the wavelengths that act most strongly in mixtures, a close approximation to William Thornton's Prime Colors. In effect, decades of research converge in three functions and a vectorial schema, demystifying such issues as color rendering and the selection of additive primaries.