“…Gibbs plot is a common tool to decisive the relationship between water composition and lithological characteristics of aquifers [36]. The Gibbs plot has three fields: precipitation dominance, evaporation dominance, and rock-water contact dominance [13,[36][37]. Samples S1, S2, S5, S8, S9, S10, S11, S12, S15, S16 and S19, experience evaporation superiority due to semi-arid environmental climate conditions and surface pollution sources, mainly excessive fertiliser usage, irrigation return flow, industrial outflows, and domestic discharges (Figure 7).…”