Approaching the 1000 K energy barrier in high coordinate lanthanide single-ion magnets: Increasing U_eff in the [Dy(Tp^2-py)F]⁺ moiety with tetrahydrofuran

Abstract

Using the existing architecture of [Dy(Tp2-py)F]+ that supports a terminal Dy-F bond, the synthesis and isolation of [Dy(Tp2-py)F(THF)2](PF6) and its diamagnetic yttrium analogue have been achieved. Alternating current magnetic susceptibility...