In this thesis, we present the new results found in exploring the asymptotic tail probability of the phase-type scale mixture distributions, and apply a subclass of the phase-type scale mixtures, the class of Erlangized scale mixture distributions, to the approximation of the probability of ruin.We consider the class of phase-type scale mixture distributions, which can be written as MellinStieltjes convolution Π G of a phase-type distribution G and a nonnegative but otherwise arbitrary distribution Π. Such a class can also be seen as the class of distributions of the product of two independent random variables: a phase-type random variable Y ∼ G and a nonnegative random variable S ∼ Π. We call S the scaling random variable and its corresponding distribution Π the scaling distribution. We investigate conditions for such a class of distributions to be either light-or heavy-tailed, we explore subexponentiality and determine their maximum domains of attraction.In this thesis, particular focus is on phase-type scale mixture distributions where the scaling distribution has discrete support -such a class has been recently used in risk applications to approximate heavy-tailed distributions. We extend an existing scheme for numerically calculating the probability of ruin of a classical Cramér-Lundberg reserve process having absolutely continuous but otherwise general claim size distributions. We employ a subclass of the phasetype scale mixtures, which is also a dense class of distributions that we denominate Erlangized scale mixtures (ESM). Such a class corresponds to nonnegative and absolutely continuous distributions which can be written as a Mellin-Stieltjes convolution Π G m of a discrete nonnegative distribution Π with an Erlang distribution G m . A distinctive feature of such a class is that it contains heavy-tailed distributions when the scaling distributions have unbounded support, and it provides sharp approximations to heavy-tailed distributions.We suggest a simple methodology for constructing a sequence of distributions having the form Π G m with the purpose of approximating the integrated tail distribution of the claim sizes.Then we adapt a recent result which delivers an explicit expression for the probability of ruin in the case that the claim size distribution is modelled as an Erlangized scale mixture. We provide simplified expressions for the approximation of the probability of ruin and construct explicit bounds for the error of approximation. We complement our results with a classical example where the claim sizes are heavy-tailed.ii