We obtain asymptotic equalities for upper bounds of approximations of functions from the classĈ ψ β,∞ by Poisson biharmonic operators in the uniform metric.LetL 1 be the set of functions ϕ defined on the entire real axis R with the finite norma∈R a+2π a |ϕ(t)|dt, letL ∞ be the space of functions measurable and essentially bounded on the entire axis with the finite norm ϕ ∞ = ess sup t∈R |ϕ(t)|, and letĈ denote the set of functions continuous and defined on the real axis with the finite norm f Ĉ = sup x∈R f (x) .Stepanets' (see, e.g., [1, 2]) introduced classesL ψ β N of functions defined on the entire real axis as follows: Let β ∈ R and a function ψ(v) continuous for all v ≥ 0 be such that the transformis summable on the entire number axis. LetL ψ β denote the set of functions f (x) ∈L 1 that can be represented in the following form for almost all x ∈ R:where A 0 is a certain constant, ϕ ∈L 1 , β ∈ R, and the integral is understood as the limit of integrals over increasing symmetric intervals.