Aquaazido{3,3′-[o-phenylenebis(nitrilomethylidyne)]di-2-naphtholato}manganese(III)

Abstract

In the title complex, [Mn(C28H18N2O2)(N3)(H2O)], the MnIII ion adopts a distorted fac-MnO3N3 octa­hedral geometry arising from the O,N,N′,O′-tetra­dentate Schiff base ligand, an azide ion and a water mol­ecule. In the crystal, inter­molecular O—H⋯(O,O) and O—H⋯N hydrogen bonds and π–π inter­actions [centroid–centroid separation = 3.5535 (13) Å] link the mol­ecules into chains.