Abstract:The title compound, [Ag(C5H5N)(H2O)](C6H4Cl2NO3S)·2H2O, has a mononuclear structure in which the Ag+ cation is two‐coordinated by one N atom from a pyridine molecule and one O atom from a water molecule. The 4‐amino‐2,5‐dichlorobenzenesulfonate anion does not coordinate to the Ag atom, but acts as a counterion. Intermolecular O—H...O hydrogen bonds link the ions and water molecules.
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