Aqueous rechargeable ammonium ion batteries based on MoS2/MXene with a ball-flower morphology as an anode and NH4V4O10 with a layered structure as a cathode

Bai, Xue; Yang, Jiahan; Zhang, Fengying; Jiang, Zhu wu; Sun, Fengyi; Pan, Chuntao; Di, Hongcheng; Ru, Shining; Liao, Dongqi; Zhang, Hongyu

doi:10.1039/d3dt00218g

Dalton Trans.

2023

DOI: 10.1039/d3dt00218g

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Aqueous rechargeable ammonium ion batteries based on MoS₂/MXene with a ball-flower morphology as an anode and NH₄V₄O₁₀ with a layered structure as a cathode

Xue Bai

Jiahan Yang

Fengying Zhang

et al.

Abstract: Due to the small hydrated ionic radius and light mol mass of ammonium ion, aqueous ammonium ion batteries attract much attention, which provides high security, environmental friendliness and low cost....

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2024

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Cited by 6 publications

References 44 publications

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Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries

Zhou,

Huang,

et al. 2024

Angewandte Chemie

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Aqueous ammonium ion batteries (AIBs) pose the advantages of high safety, low cost, and high efficiency, capturing substantial research interest. The intrinsic chemical properties of NH4+ promote the formation of hydrogen bonds with other constituents in AIBs, critically influencing the processes of NH4+ transfer, storage, and diffusion. This review delves into the pivotal role of hydrogen bonding chemistry in AIBs. Firstly, the principles of hydrogen bond are elucidated as the dominant chemical interaction governing NH4+ dynamics in AIBs. Subsequently, a detailed analysis is conducted on the impacts of hydrogen bonds in both electrolytes and electrode materials. Furthermore, the practical applications of hydrogen bonding chemistry within the context of AIBs are assessed. Finally, strategic insights and future research directions are proposed to harness hydrogen bonding effects for optimizing AIB performance. This review aims to define the mechanisms and impacts of hydrogen bonds in AIBs, providing robust strategies to enhance electrochemical performance, deepen the understanding of energy storage mechanisms, and guide the future advancement of AIBs technology.

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Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries

Zhou,

Huang,

et al. 2024

Angewandte Chemie

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Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries

Zhou,

Huang,

et al. 2024

Angew Chem Int Ed

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Incorporation of Organic Benzoquinone Framework Into rGO via Strong π–π Interaction for High‐Performance Aqueous Ammonium‐Ion Battery

Tang,

Zhang,

Sun

et al. 2024

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Aqueous ammonium‐ion batteries (AAIBs) are promising candidates for next‐generation energy storage devices. However, organic materials as suitable anodes face severe challenges due to their structural instability and poor conductivity, which hinder the development of AAIBs. Herein, an innovative approach is introduced by incorporating an organic benzoquinone framework, 5,7,11,14‐tetraaza‐6,13‐pentacenequinone (TAPQ), with reduced graphene oxide (rGO) using a solvent exchange method. Benefiting from π–π interaction and electron delocalization, TAPQ/rGO features enhanced cycling stability and ion/electron transportation. Consequently, the composite electrode delivers a reversible capacity of 181.7 mAh g−1 at 0.5 A g−1 and achieves an ultrahigh capacity retention of 94.5% over 10 000 cycles at 5 A g−1, surpassing most reported anodes in AAIBs. Combining density functional theory (DFT) calculation and ex situ electrochemical characterizations, the unique storage mechanism of chelation coordination between NH4+ and N, O is revealed. Furthermore, a high‐performance NH4+‐based full cell, assembled with TAPQ/rGO anode and copper hexacyanoferrate (Cu‐HCF) cathode, demonstrates long‐term cycling stability with 93.95% capacity retention after 500 cycles. This work pioneers the concept of π–π interactions to significantly improve NH4+ storage performance, presenting a novel strategy for the advancement of AAIBs research.

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Aqueous rechargeable ammonium ion batteries based on MoS₂/MXene with a ball-flower morphology as an anode and NH₄V₄O₁₀ with a layered structure as a cathode

Abstract: Due to the small hydrated ionic radius and light mol mass of ammonium ion, aqueous ammonium ion batteries attract much attention, which provides high security, environmental friendliness and low cost....

Cited by 6 publications

References 44 publications

Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries

Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries

Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries

Incorporation of Organic Benzoquinone Framework Into rGO via Strong π–π Interaction for High‐Performance Aqueous Ammonium‐Ion Battery

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