The
work of separation (W
sep), interface
energy (γint), and electronic properties of Ag/M
(M = Ni, Cu, W, and Pd) and Cu/Cr interfaces are systematically studied
by using first-principles calculations. Three criteria, W
sep, γint, and the quantum conductivity
(G), have been proposed for the suitable electrical
contact materials. The results indicate that Ag(111)/Ni(111), Ag(100)/W(100),
and Ag(111)/W(110) interfaces have comparatively larger W
sep and lower positive γint among all
the interfaces, which demonstrates that Ag/Ni and Ag/W interfaces
are more suitable as nano-multilayer electrical contact materials
than other interfaces. Moreover, the Ag(111)/Ni(111) interface has
the largest G and the best dispersing arc ability
among these three interfaces, and thus, it is chosen as the best candidate
for the interface of nano-multilayer electrical contact material.