Lead (Pb) is widely distributed in the environment and its negative health effects, especially to children, have been well documented. The aqueous species of Pb, in their form and concentration, strongly depend on mineral–water interaction processes in the environment. Lead exists in the environment mostly in the form of solid particles but bioavailable toxic Pb is absorbed by living organisms through solution. Therefore, our understanding of formation, transformation, dissolution, and precipitation of Pb‐bearing phases in aqueous solutions is critical for successful strategies to minimize Pb in drinking water or food and to prevent exposure and poisoning. This article summarizes our current understanding of processes governing the presence of Pb in waters and soils, briefly discusses Pb toxicity, and reviews some key technologies for immobilizing Pb and making it less bioavailable. Finally, the article ends with some suggestions for further research.