The work explores the asymptotic properties of large-dimensional stochastic matrices N under the condition of independence of matrix elements or rows (columns). An analysis of the main properties of eigenvalues of stochastic matrices is conducted. The work is dedicated to investigating the asymptotic characteristics of random matrices under the absence of the second moment and also considers the presence of "heavy tails" in the corresponding transitions in the adjacency matrices of the respective graph. The main result of the work is formulated in terms of the transition matrix of a discrete Markov chain and its eigenvalues. In proving the theorem, a non-degenerate Markov chain is considered, describing a mathematical model of random processes that do not change over time with known transition probabilities between states and a corresponding stochastic matrix P, one of whose eigenvalues is unity, and all eigenvalues of the stochastic matrix do not exceed it in absolute value. The proof of this fact follows from the Perron–Frobenius theorem, which concerns the properties of positive matrices and their eigenvalues. Thus, the theorem considered manages to expand the class of random matrices A for which convergence of eigenvalues of the matrix can be applied under the conditions imposed on the elements of the adjacency matrix. Moreover, the imposed conditions are relaxed compared to classical results, where the existence of a finite second moment for the elements of the adjacency matrix is required. This result generalizes both classical results for the normal distribution and similar results of other authors. The obtained result can be used in graph clustering problems to choose the optimal number of clusters, namely, they can be applied to determine the optimal number of clusters in a Grid system, complex networks, in investigations of the structure of the web space, etc.