Formation of various Sm-Ba-Cu-O phases grown under thermal equilibrium on (010) surfaces of Sm 2 BaCuO 5 single-crystalline whiskers was observed in situ by means of a high-temperature optical microscope. At 1100°C a needle-like phase, identified by X-ray diffraction and energy-dispersive spectroscopy analyses as Sm 2 Ba 4 Cu 2 O y , grew epitaxially on the whisker (010) surface. After being cooled to 1050°C (close to the peritectic temperature, T p ), the SmBa 2 Cu 3 O y (Sm-123) phase nucleated and grew epitaxially in two different orientations: [100] Sm-123 //[001] Sm-123 //[001] Sm-211 . During a slow reheating, the former type of Sm-123 grains preferentially decomposed, indicating its lower thermal stability with respect to the latter type of grains.